We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Neutral color and self-healable electrochromic system based on CuI/Cu and I3−/I− conversions.
- Authors
Zhong, Junsen; Huang, Bingkun; Yang, Kunjie; Ma, Zuju; Du, Lingyu; Luo, Ning; Tang, Fengjiao; Hou, Chuanxin; Jiang, Fuyi; Kang, Litao
- Abstract
The electrochromic (EC) mechanisms of inorganic materials are usually based on reversible cation insertion/extraction or metal deposition/dissolution, which are plagued by ion trapping and dendrite growth, respectively. In this paper, a novel conversion-type electrochromic mechanism is proposed, by making good use of the CuI/Cu redox couple. This CuI-based electrochromic system shows a neutral color switching from transparent and dim grey. By simply increasing the bleaching voltage, I 3 − / I − redox couple can be further activated. The generated I 3 − will readily react with Cu, effectively improving the conversion reversibility and thereby rejuvenating the degraded electrochromic performance. Thanks to the well-designed electrode and the self-healing ability, this conversion electrochromic system achieves rapid response times (tcoloring: 23 s, tbleaching: 6 s), decant optical modulation amplitude (26.4%), high coloration efficiency (86.15 cm2·C−1), admirable cyclic durability (without performance degradation after 480 cycles) and excellent optical memory ability (transmittance variation < 1% after 10 h open-circuit storage). The establishment of this conversion-type electrochromism may inspire the exploration of novel electrochromic materials and devices.
- Subjects
COPPER; ELECTROCHROMIC effect; OPTICAL modulation; ELECTROCHROMIC substances; ION traps; ELECTROCHROMIC devices
- Publication
Nano Research, 2024, Vol 17, Issue 5, p4437
- ISSN
1998-0124
- Publication type
Article
- DOI
10.1007/s12274-023-6322-6