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- Title
Preparation and characteristic of a sodium alginate/carboxymethylated bacterial cellulose composite with a crosslinking semi-interpenetrating network.
- Authors
Lin, Qinghua; Zheng, Yudong; Ren, Lingling; Wu, Jian; Wang, Hong; An, Jiaxin; Fan, Wei
- Abstract
ABSTRACT A novel ionic crosslinking sodium alginate (SA)/carboxymethylated bacterial cellulose (CM-BC) composite with a semi-interpenetrating polymer network (semi-IPN) structure was developed in this study. The composite was prepared through the blending of an SA gel with CM-BC then crosslinking by Ca2+ followed by a freeze-drying process. Scanning electron microscopy showed the composite matrix organized in a three-dimensional network of CM-BC interpenetrated against SA molecular chains with a quantity of calcium alginate microspheres upon the surface. The swelling ratios of the composite were enhanced by 183, 198, and 212% with the supplementation of CM-BC weight fractions of 25, 50, and 75%, respectively; the swelling ratios changed with changing pH. The tensile modulus, tensile strength, and elongation at break of SA were enhanced by 165, 152, and 188%, respectively, with the addition of 50 wt % CM-BC. This study demonstrated that the semi-IPN structure dramatically changed the swelling and mechanical properties of the composite, and the semi-IPN will be a promising candidate for biomedical applications such as wound dressings and skin tissue engineering. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 39848.
- Subjects
SODIUM alginate; CARBOXYMETHYLATION; CELLULOSE; POLYMER networks; BIOMATERIALS; SURGICAL dressings
- Publication
Journal of Applied Polymer Science, 2014, Vol 131, Issue 3, pn/a
- ISSN
0021-8995
- Publication type
Article
- DOI
10.1002/app.39848