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- Title
Catalytic Enantioselective Assembly of Homoallylic Alcohols from Dienes, Aryldiazonium Salts, and Aldehydes.
- Authors
Tao, Zhong‐Lin; Adili, Alafate; Shen, Hong‐Cheng; Han, Zhi‐Yong; Gong, Liu‐Zhu
- Abstract
A highly selective multicomponent carbonyl allylation reaction of 1,3-butadienes, aryldiazonium tetrafluoroborates, and aldehydes has been established under the combined catalysis of palladium acetate and chiral anion phase transfer to render the favorable assembly of chiral Z-configured homoallylic alcohols in high yields and with excellent levels of enantioselectivity.
- Subjects
ALLYL alcohol synthesis; ASYMMETRIC synthesis; CARBONYL compounds; CHEMICAL synthesis; DIOLEFINS synthesis; ALDEHYDE synthesis; PALLADIUM catalysts; PHASE-transfer catalysis
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 13, p4322
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201600148