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- Title
Selective Reductive Coupling of Nitro Compounds with Aldehydes to Nitrones in H<sub>2</sub> Using Carbon-Supported and -Decorated Platinum Nanoparticles.
- Authors
Cisneros, Larisha; Serna, Pedro; Corma, Avelino
- Abstract
Nitrones were synthesized in high yields directly from nitro compounds, aldehydes, and H2 using carbon-decorated platinum nanoparticles. The high selectivity for nitrone synthesis contrasts that of common supported metal catalysts and corresponds to an increase from roughly 6 to 97 %. The catalytic performance is tuned by precise control of the structure of the active sites and the characteristics of the support.
- Subjects
NITRONE derivatives; NITRO compounds; ALDEHYDES; NANOPARTICLES; CATALYTIC activity; METAL catalysts
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 35, p9306
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201402878