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- Title
Modulation of Chiroptical and Photophysical Properties in Helicenic Rhenium(I) Systems: The Use of an N‐(Aza[6]helicenyl)‐NHC Ligand.
- Authors
Gauthier, Etienne S.; Abella, Laura; Caytan, Elsa; Roisnel, Thierry; Vanthuyne, Nicolas; Favereau, Ludovic; Srebro‐Hooper, Monika; Williams, J. A. Gareth; Autschbach, Jochen; Crassous, Jeanne
- Abstract
The photophysical and chiroptical properties of a novel, chiral helicene‐NHC−Re(I) complex bearing an N‐(aza[6]helicenyl)‐benzimidazolylidene ligand are described, showing its ability to emit yellow circularly polarized luminescence. A comparative analysis of this new system with other helicene‐Re(I) complexes reported to date illustrates the impact of structural modifications on the emissive and absorptive properties.
- Subjects
RHENIUM; LUMINESCENCE
- Publication
Chemistry - A European Journal, 2023, Vol 29, Issue 21, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202203477