We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Frontispiece: Diverse Approaches for Enantioselective C−H Functionalization Reactions Using Group 9 Cp<sup>x</sup>M<sup>III</sup> Catalysts.
- Authors
Yoshino, Tatsuhiko; Satake, Shun; Matsunaga, Shigeki
- Abstract
C−H activation with cyclopentadienyl complexes: Transition‐metal‐catalyzed C−H functionalization reactions with Cp*MIII catalysts (M=Co, Rh, Ir) have found a wide variety of applications in organic synthesis. Albeit the intrinsic difficulties in achieving catalytic stereocontrol using these catalysts due to their lack of additional coordination sites for external chiral ligands and the conformational flexibility of the Cp ligand, catalytic enantioselective C−H functionalization reactions using the Group 9 metal triad with Cp‐type ligands have been intensively studied since 2012. In this Minireview on page 7346 ff., T. Yoshino, S. Satake and S. Matsunaga summarize and discuss the progress in these reactions according to the type of the chiral catalyst used. The development of chiral Cpx ligands and their metal complexes, artificial metalloenzymes, chiral carboxylate‐assisted enantioselective C−H activations, enantioselective alkylations assisted by chiral carboxylic acids or chiral sulfonates, and chiral transient directing groups are discussed.
- Publication
Chemistry - A European Journal, 2020, Vol 26, Issue 33, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201905417