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- Title
Tetrazine Linkers as Plug‐and‐Play Tags for General Metal‐Organic Framework Functionalization and C<sub>60</sub> Conjugation.
- Authors
Lerma‐Berlanga, Belén; Ganivet, Carolina R.; Almora‐Barrios, Neyvis; Vismara, Rebecca; Navarro, Jorge A. R.; Tatay, Sergio; Padial, Natalia M.; Martí‐Gastaldo, Carlos
- Abstract
The value of covalent post‐synthetic modification in expanding the chemistry and pore versatility of reticular solids is well documented. Here we use mesoporous crystals of the metal–organic framework (MOF) UiO‐68‐TZDC to demonstrate the value of tetrazine connectors for all‐purpose inverse electron‐demand Diels–Alder ligation chemistry. Our results suggest a positive effect of tetrazine reticulation over its reactivity for quantitative one‐step functionalization with a broad scope of alkene or alkyne dienophiles into pyridazine and dihydropyridazine frameworks. This permits generating multiple pore environments with diverse chemical functionalities and the expected accessible porosities, that is also extended to the synthesis of crystalline fulleretic materials by covalent conjugation of fullerene molecules.
- Subjects
METAL-organic frameworks; TETRAZINE; ALKENES; DIENOPHILES; CLICK chemistry; FULLERENES; PYRIDAZINES
- Publication
Angewandte Chemie, 2022, Vol 134, Issue 41, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202208139