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- Title
Dinuclear Mn(I) Complexes with Phosphido and Hydrido Bridges: Synthesis, Reactivity, and Hydrogenative Catalysis.
- Authors
Lacy, David C.; Abhyankar, Preshit C.
- Abstract
A class of organomanganese hydrogenation catalysts was recently rediscovered. These are simple dinuclear Mn(I) carbonyl compounds with phosphido (PR2−) and hydrido (H−) bridges. This class of compounds has been known since the 1960's, and they have rich coordination chemistry and reactivity. Given their recently discovered potential for catalytic applications, a fresh look at this class of compounds was necessary. Hence, this Review comprehensively covers the synthesis, reactivity, and catalysis of this interesting class of molecules.
- Subjects
CATALYSIS; REACTIVITY (Chemistry); CARBONYL compounds; HYDROGENATION; CATALYSTS
- Publication
Chemistry - A European Journal, 2023, Vol 29, Issue 36, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202300518