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- Title
Calculation of the Radiative Parameters for the (2)2Σ+–X2Σ+ Electronic Transition of NaK+ and NaCs+ Molecular Ions.
- Authors
Smirnov, A. D.
- Abstract
Einstein spontaneous radiation coefficients, absorption oscillator strengths, Franck–Condon factors, wavenumbers of vibronic transitions in (2)2Σ+–X2Σ+ band systems of NaK+ (0 ≤ v′ ≤ 14, 0 ≤ v′′ ≤ 100) and NaCs+ molecular ions (0 ≤ v′ < 14, 0 ≤ v′′ ≤ 69), and excited electronic-state radiative lifetimes are calculated using Hulburt–Hirschfelder potential curves for ground and excited electronic states that were constructed using published ab initio calculations. Vibrational energies and the corresponding wave functions necessary to calculate radiative parameters were found by numerical solution of the Schrödinger equation.
- Subjects
IONS; FRANCK-Condon principle; OSCILLATOR strengths; NUMERICAL solutions to equations; EINSTEIN coefficients; WAVE functions
- Publication
Journal of Applied Spectroscopy, 2019, Vol 86, Issue 1, p27
- ISSN
0021-9037
- Publication type
Article
- DOI
10.1007/s10812-019-00776-7