We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Ynones in Reflex‐Michael Addition, CuAAC, and Cycloaddition, as Well as their Use as Nucleophilic Enols, Electrophilic Ketones, and Allenic Precursors.
- Authors
Wang, Zhan‐Yong; Wang, Kai‐Kai; Chen, Rongxiang; Liu, Huan; Chen, Kaijun
- Abstract
The great success of ynones in synthesis is rooted in their multiple functional groups. Herein, reactions triggered by the reflex‐Michael addition, ynones in copper(I)‐catalyzed alkyne–azide cycloaddition (CuAAC), and formal cycloaddition as well as the use of ynones as nucleophilic enols, electrophilic ketones, and allenic precursors were thoroughly discussed and summarized. Multi‐component reactions, rearrangements, cycloadditions, regio‐ and stereoselective synthesis, coupling, and cycloaddition are depicted in detail. This review focused on advances of ynones chemistry in the last decade (2009–2019). We hope it will promote future research in this area.
- Subjects
ENOLS; RING formation (Chemistry); KETONES; AZIDATION; FUNCTIONAL groups
- Publication
European Journal of Organic Chemistry, 2020, Vol 2020, Issue 17, p2456
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201901921