We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Reply To: How Does Substitutional Doping Affect Visible Light Absorption in a Series of Homodisperse Ti<sub>11</sub> Polyoxotitanate Nanoparticles-A Comment on the Band Gap Determination of the Fe<sup>II</sup> Cages.
- Authors
Chen, Yang; Jarzembska, Katarzyna N.; Trzop, Elzbieta; Coppens, Philip
- Abstract
A summary of the evidence based on spectroscopy, calculated density of states (DOS) and photo‐electrochemistry, for electron transfer from the occupied Fe2+(d)‐β orbital located within the band gap of the [Ti4O(OEt)15(FeBr)] cluster, to its unoccupied Ti(d) orbitals is presented. The importance of the distinction between the concepts of band gap and HOMO–LUMO gap is emphasized.
- Subjects
STRUCTURE-activity relationships; BIOCHEMICAL research; PHYSICAL &; theoretical chemistry research; BAND gaps; DENSITY of states
- Publication
Chemistry - A European Journal, 2016, Vol 22, Issue 13, p4634
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201600041