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- Title
NMO⋅TPB: A Selectivity Variation on the Ley-Griffith TPAP Oxidation.
- Authors
Moore, Peter W.; Mirzayans, Paul M.; Williams, Craig M.
- Abstract
A non-hygroscopic tetraphenylborate salt of N-methylmorpholine- N-oxide (NMO) is reported (NMO ⋅TPB), which modulates the standard Ley-Griffith oxidation such that benzylic and allylic alcohols are oxidised selectively. An attractive feature of this new protocol is that anhydrous conditions are not required for this selective tetra- n-propylammonium perruthenate (TPAP) oxidation, superseding the requirement of molecular sieves.
- Subjects
NITROGEN oxides; ALLYL alcohol; OXIDATION; TETRAPHENYLBORATES; BENZYLIC group
- Publication
Chemistry - A European Journal, 2015, Vol 21, Issue 9, p3567
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201406256