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- Title
Effect of spin-orbit coupling on the magnetic susceptibility of polynuclear complexes of 3 d metals containing a Co ion.
- Authors
Litvinenko, A.; Mikhaleva, E.; Kolotilov, S.; Pavlishchuk, V.
- Abstract
Using a program we developed allowing us to take into account zero-field splitting, spin-orbit, and exchange interactions in polynuclear complexes, we have interpreted the temperature dependences of the magnetic susceptibility for the complexes FeCoO(CFCO)(HO)·HO ( 1) and [Co(HO)][CuL(HO)]·3HO ( 2, HL = 1,9-dicyano- 1,9-bis(hydroximino)-3,7-diazanonane-2,8-dione). We have analyzed the differences between the values of the simulation parameters determined within different theoretical models.
- Subjects
COBALT compounds; MAGNETIC susceptibility; MAGNETOCHEMISTRY; EXCHANGE reactions; COMPUTER simulation; MATHEMATICAL models; COMPLEX compounds
- Publication
Theoretical & Experimental Chemistry, 2011, Vol 46, Issue 6, p422
- ISSN
0040-5760
- Publication type
Article
- DOI
10.1007/s11237-011-9174-1