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- Title
Direct Reductive <italic>N</italic>‐Functionalization of Aliphatic Nitro Compounds.
- Authors
Rauser, Marian; Ascheberg, Christoph; Niggemann, Meike
- Abstract
Abstract: The first general protocol for the direct reductive <italic>N</italic>‐functionalization of aliphatic nitro compounds is presented. The nitro group is partially reduced to a nitrenoid, with a mild and readily available combination of B2pin2 and zinc organyls. Thereby, the formation of an unstable nitroso intermediate is avoided, which has so far severely limited reductive transformations of aliphatic nitro compounds. The reaction is concluded by an electrophilic amination of zinc organyls.
- Subjects
ZINC; NITRO compounds; ELECTROPHILIC substitution reactions; ORGANYL groups; ALIPHATIC compounds
- Publication
Chemistry - A European Journal, 2018, Vol 24, Issue 16, p3970
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201705986