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- Title
Mononuclear Alkali Metal Organoperoxides Stabilized by an NNNN-Macrocycle and Short Hydrogen Bonds from ROOH Molecules.
- Authors
Osseili, Hassan; Truong, Khai‐Nghi; Spaniol, Thomas P.; Mukherjee, Debabrata; Englert, Ulli; Okuda, Jun
- Abstract
A series of light alkali metal organoperoxides [MOOR] (M=Li, Na, K; R= tBu, CMe2Ph) were isolated in mononuclear form, aided by the tetradentate and neutral NNNN-type macrocycle Me4TACD (L; Me4[12]aneN4=1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) and strong hydrogen bonds from additional ROOH molecules. The Na and K compounds are characterized by short O−H⋅⋅⋅O contacts, in the case of the Na derivative as short as 2.41 Å.
- Subjects
ALKALI metals; HYDROGEN bonding; TETRAMETHYL compounds; SODIUM compounds; POTASSIUM compounds
- Publication
Chemistry - A European Journal, 2017, Vol 23, Issue 68, p17213
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201704758