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- Title
Noncovalent Functionalization of Black Phosphorus.
- Authors
Abellán, Gonzalo; Lloret, Vicent; Mundloch, Udo; Marcia, Mario; Neiss, Christian; Görling, Andreas; Varela, Maria; Hauke, Frank; Hirsch, Andreas
- Abstract
Black phosphorus (BP) was functionalized with organic moieties on the basis of liquid exfoliation. The treatment of BP with electron-withdrawing 7,7,8,8-tetracyano- p-quinodimethane (TCNQ) led to electron transfer from BP to the organic dopant. On the other hand, the noncovalent interaction of BP with a perylene diimide was mainly due to van der Waals interactions but also led to considerable stabilization of the BP flakes against oxygen degradation.
- Subjects
PHOSPHORUS compounds; FUNCTIONAL groups; OXIDATION-reduction reaction; QUINODIMETHANE; DOPING agents (Chemistry); PERYLENE derivatives; IMIDES
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 47, p14777
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201604784