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- Title
Encapsulating Palladium Nanoparticles Inside Mesoporous MFI Zeolite Nanocrystals for Shape-Selective Catalysis.
- Authors
Cui, Tian ‐ Lu; Ke, Wen ‐ Yu; Zhang, Wen ‐ Bei; Wang, Hong ‐ Hui; Li, Xin ‐ Hao; Chen, Jie ‐ Sheng
- Abstract
Pd nanoparticles were successfully encapsulated inside mesoporous silicalite-1 nanocrystals (Pd@mnc-S1) by a one-pot method. The as-synthesized Pd@mnc-S1 with excellent stability functioned as an active and reusable heterogeneous catalyst. The unique porosity and nanostructure of silicalite-1 crystals endowed the Pd@mnc-S1 material general shape-selectivity for various catalytic reactions, including selective hydrogenation, oxidation, and carbon-carbon coupling reactions.
- Subjects
ENCAPSULATION (Catalysis); PALLADIUM compounds; ZEOLITES; SHAPE-selective catalysis; SILICALITE; HYDROGENATION; COUPLING reactions (Chemistry)
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 32, p9324
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201602429