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- Title
Inside Back Cover: Charge Control in Two Isostructural Anionic/Cationic Co<sup>II</sup> Coordination Frameworks for Enhanced Acetylene Capture (Chem. Eur. J. 42/2016).
- Authors
Chen, Di‐Ming; Tian, Jia‐Yue; Liu, Chun‐Sen; Chen, Min; Du, Miao
- Abstract
Charge control of isostructural metal–organic frameworks (MOFs) can be achieved by ligand modulation with similar bifunctional linkers with carboxylate and azole groups, giving a pair of comparable anionic and cationic porous frameworks with the inclusion of HN(CH3)2+ and NO3− as the counterions. Interestingly, the cationic CoII–MOF showed an 88% increase in C2H2 uptake at 298 K compared with the anionic analogue, demonstrating the critical role of framework charge and/or guest anion on their gas‐capture behaviors. More information can be found in the Full Paper by C.‐S. Liu, M. Du et al. on page 15035 ff.
- Subjects
CHEMISTRY; ACETYLENE
- Publication
Chemistry - A European Journal, 2016, Vol 22, Issue 42, p15151
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201603981