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- Title
P(V)-Promoted Rh-Catalyzed Highly Regioselective Hydroformylation of Styrenes under Mild Conditions.
- Authors
Ru, Tong; Zhang, Yajiao; Wei, Qiuxiang; Zuo, Sheng; Jia, Zhenhua; Chen, Fen-Er
- Abstract
Hydroformylation of olefins is widely used in the chemical industry due to its versatility and the ability to produce valuable aldehydes with 100% atom economy. Herein, a hybrid phosphate promoter was found to efficiently promote rhodium-catalyzed hydroformylation of styrenes under remarkably mild conditions with high regioselectivities. Preliminary mechanistic studies revealed that the weak coordination between the Rhodium and the P=O double bond of this pentavalent phosphate likely induced exceptional reactivity and high ratios of branched aldehydes to linear products.
- Subjects
HYDROFORMYLATION; STYRENE; DOUBLE bonds; CHEMICAL industry; RHODIUM
- Publication
Molecules, 2024, Vol 29, Issue 9, p2039
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules29092039