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- Title
Anhydrous Dinitrogen Trioxide Solutions for Brønsted Acid Free Nitrous Acid Chemistry.
- Authors
Rosadiuk, Kristopher A.; Bohle, D. Scott
- Abstract
Dinitrogen trioxide, N2O3, is readily prepared and stabilized in high concentrations in dry organic solvents at normal working temperatures. These conditions allow for facile acid and water free nitrosation and nitration reactions for which three examples are given here: the preparation of benzenediazonium nitrite, [PhN2][NO2]; nitrosyl chloride, NOCl, and nitrosylsulfuric acid, (ONOSO3H).
- Subjects
NITROGEN fixation; ORGANIC solvents; NITROSATION; NITROSYL chloride; BIOGEOCHEMICAL cycles
- Publication
European Journal of Inorganic Chemistry, 2017, Vol 2017, Issue 46, p5461
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201701091