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- Title
Three-in-One Crystal: The Coordination Diversity of Zinc Polypyridine Complexes.
- Authors
Otto, Sven; Moll, Johannes; Förster, Christoph; Geißler, Daniel; Wang, Cui; Resch‐Genger, Ute; Heinze, Katja
- Abstract
The syntheses, structures, and photophysical properties of two new zinc(II) complexes bearing the tridentate N,N'-dimethyl-N,N'-dipyridin-2-ylpyridine-2,6-diamine (ddpd) ligand are presented. Structural investigations through single-crystal X-ray diffractometry, NMR spectroscopy, and density functional theory calculations revealed a diverse coordination behavior that depends on the counterion. Spectroscopic (UV/Vis and emission spectroscopy) and theoretical techniques (DFT and time-dependent DFT calculations) were employed to explore the photophysical properties of the complexes.
- Subjects
COORDINATE covalent bond; ZINC compounds; POLYPYRIDINES; METAL complexes; CRYSTAL structure; COMPLEX compounds synthesis
- Publication
European Journal of Inorganic Chemistry, 2017, Vol 2017, Issue 43, p5033
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201700948