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- Title
Reaction of Tricyclo[4.1.0.02,7]heptane with 1-(Arenesulfonyl)-2-phenyldiazenes.
- Authors
Kostryukov, S. G.; Masterova, Yu. Yu.
- Abstract
Tricyclo[4.1.0.02,7]heptane reacted with 1-(arenesulfonyl)-2-phenyldiazenes by radical mechanism to give bicyclo[3.1.1]heptane derivatives. Unlike analogous reactions with alkenes, the addition of diazenes occurs readily without a catalyst and yields mainly arylazosulfonation products at the C1–C7 bond of tricyclo-[4.1.0.02,7]heptane. The addition products are capable of undergoing thermal prototropic isomerization to 7-endo-(arenesulfonyl)bicyclo[3.1.1]heptan-6-one phenylhydrazones.
- Subjects
DIAZENES; ISOMERIZATION; HEPTANE; CATALYSTS
- Publication
Russian Journal of Organic Chemistry, 2020, Vol 56, Issue 4, p576
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S107042802004003X