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- Title
Effect of Chemical Modification of the Tetrapyrrole Macrocycle Structure on the Spectral, Acid–Base, and Complexing Properties of tert-Butyl-Substituted Porphyrazines.
- Authors
Ivanova, Yu. B.; Semeikin, A. S.; Lyubimova, T. V.; Mamardashvili, N. Zh.
- Abstract
The effect of chemical modification of the tetrapyrrole macrocycle structure on the spectral, acid–base, and complexing properties of tetrakis[5,6-bis(4-tert-butylphenyl)pyrazino]porphyrazine, tetra(4-tert-butyl)phthalocyanine, and octakis(4-tert-butylphenyl)porphyrazine in acetonitrile at 298–318 K has been studied by 1H NMR, electronic spectroscopy, and mass spectrometry. The obtained results can be used in the design of macrocyclic tetrapyrrole functional materials with desired physicochemical properties.
- Subjects
PORPHYRAZINES; MASS spectrometry; PHTHALOCYANINE derivatives; ACETONITRILE; METAL phthalocyanines
- Publication
Russian Journal of Organic Chemistry, 2020, Vol 56, Issue 10, p1691
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428020100036