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- Title
Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative.
- Authors
Veselovsky, Vladimir V.; Isaeva, Vera I.; Nissenbaum, Vera D.; Kustov, Leonid M.; Chernyshev, Vladimir V.
- Abstract
The new homochiral 1D metal–organic coordination polymer [Cu2(EDPB)•H2O]n was synthesized starting from the original 3,3′-ethyne-1,2-diylbis[6-(L-prolylamino)benzoic acid] (H4EDPB). The unique crystal structure of the new compound was established by powder X-ray diffraction. The [Cu2(EDPB)•H2O]n system shows catalytic activity and enantioselectivity in a Henry reaction of p-nitrobenzaldehyde with nitromethane.
- Subjects
COORDINATION polymers; ACID derivatives; CRYSTAL structure; X-ray powder diffraction; NITROALDOL reactions; BENZOIC acid
- Publication
Molecules, 2022, Vol 27, Issue 23, p8376
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules27238376