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- Title
2-(1,2,3-Triazol-4-yl)-imidazoline, -oxazoline, -thiazoline and -tetrahydropyrimidine as ligands in copper(II) and nickel(II) complexes.
- Authors
Schröder, Sven; Frey, Wolfgang; Maas, Gerhard
- Abstract
2-(1-Benzyl-1 H-1,2,3-triazol-4-yl)-imidazolines ( L1 and L2/ L2′), -1,3-oxazoline ( L3), -1,3-thiazoline ( L4) and -tetrahydropyrimidine ( L5) were prepared in one step from a 1,2,3-triazole-4-carboxamidinium tetraphenylborate and studied as novel ligands for copper(II) and nickel(II) ions. The solid-state structures of the following complexes were established: [Cu( L1)2](OTf)2, [Cu L2L2′(OTf)2] · 2H2O, [[Cu( L4)2(H2O)2](OTf)2 · [Cu( L4)2(OTf)2], [Cu( L5)2(OTf)2], Cu( L3)2Cl2] · THF, [Ni( L1)2Cl2].
- Subjects
IMIDAZOLINES; OXAZOLINE; THIAZOLINES; COPPER; NICKEL; SOLID state chemistry
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2016, Vol 71, Issue 6, p683
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2016-0026