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- Title
Syntheses and structural characterization of coordination polymers of Cu(II) and Zn(II) chlorobenzoates and bis(pyridin-4-yl)-substituted species.
- Authors
Mao, Fu-Lin; Tao, Jian-Qing; Dai, Chun-Hua
- Abstract
The reaction of Cu(II) nitrate with sodium 2-chlorobenzoate (NaL1) and (E)-1,2-di(pyridin-4-yl)ethene (dpe) yields a new complex [Cu(L1)2(dpe)(H2O)] (1). When Zn(II) nitrate reacts with sodium 4-chlorobenzoate (NaL2) and 1,2-di(pyridin-4-yl)ethane (dpa), [Zn(L2)2(dpa)]·CH3OH (2) is obtained. Complexes 1 and 2 have been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. 1 shows a 3D CdS network structure with uninodal 4-connected (65.8) topology; complex 2 displays a chain structure.
- Subjects
NITRATES; SODIUM; ALKENES; ETHANES; TOPOLOGY; X-ray diffraction
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2015, Vol 70, Issue 2, p95
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2014-0193