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- Title
Synthesis of new metallomesogens based on 3-ketoesters.
- Authors
Kovganko, V.; Kovganko, N.
- Abstract
Ethyl 3-(4-hydroxyphenyl)-3-ketopropionate was synthesized by acylation of acetoacetic ester with 4-acetoxybenzoyl chloride, followed by cleavage of aroylacetoacetic ester and hydrolysis of the protecting acetate group. Further esterification of the phenol hydroxy group with 4-alkoxybenzoic acids resulted in the synthesis of mesogenic 3-aryl-3-keto ester used to produce copper(II) metallomesogenic complexes.
- Subjects
METALLOMESOGENS; ACETAMINOPHEN; HYDROLYSIS kinetics; ETHYL acetoacetate; MESOGENIC groups; ETHYL chloride
- Publication
Russian Journal of General Chemistry, 2013, Vol 83, Issue 8, p1556
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363213080148