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- Title
Controlled Polymerization.
- Authors
Ivchenko, Pavel V.
- Abstract
Atom transfer radical polymerization (ATRP), reversible addition/fragmentation chain transfer polymerization (RAFT), and nitroxide-mediated polymerization (NMP) are common examples of controlled polymerization processes. On the contrary, the Zn complex efficiently catalyzed random I L i -LA/ CL copolymerization; the presence of mono-lactate subunits in the copolymer clearly verified the transesterification mechanism of copolymer formation, and the Al complex was less active. An amazing variety of polymerization mechanisms enables the creation of polymers with given microstructures and comonomer sequences.
- Subjects
LIVING polymerization; CATALYTIC polymerization; METHYL methacrylate; CONJUGATED polymers; RING-opening polymerization; BLOCK copolymers; PHOSPHONATES
- Publication
Polymers (20734360), 2023, Vol 15, Issue 6, p1379
- ISSN
2073-4360
- Publication type
Article
- DOI
10.3390/polym15061379