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- Title
Isomerization of Secondary Phosphirane into Terminal Phosphinidene Complexes: An Analogy between Monovalent Phosphorus and Transition Metals.
- Authors
Wong, Jonathan; Li, Yongxin; Hao, Yanwei; Tian, Rongqiang; Mathey, François
- Abstract
Secondary phosphirane complexes isomerize above 100 °C to give the corresponding terminal phosphinidene complexes, which can be trapped by alkenes and alkynes. This reaction is a rare instance of the isomerization of a PIII derivative into a PI derivative. It appears to mimic the reductive elimination of alkanes from transition-alkylmetal hydrides.
- Subjects
ISOMERIZATION; METAL complexes; TRANSITION metals; CHEMICAL reactions; CHEMICAL derivatives
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 44, p13083
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201504869