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- Title
Stereoselektive reduktive Dimerisierung von α-Cyan-β-(4-pyridyl)acrylsäurederivaten.
- Authors
Kompis, Ivan; Schönholzer, Peter
- Abstract
Stereoselective Reductive Dimerisation of α-Cyano-β-(4-pyridyl)acrylic Acid Derivatives Catalytic hydrogenation of the α-substituted β-(4-pyridyl)acrylonitriles 3 and 4 (see Scheme 3) yields via stereoselective reductive dimerization the substituted cyclo-pentene derivatives 7 and 8 (see Scheme 4 and 5) instead of the expected dihydro-products 5 and 6. The mechanism of this reaction is discussed. The structure and relative configuration of 10 have been established by X-ray single crystal analysis.
- Publication
Helvetica Chimica Acta, 1977, Vol 60, Issue 2, p618
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19770600234