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- Title
New Horizons in Chemical Functionalization of Endohedral Metallofullerenes.
- Authors
Yamada, Michio; Liu, Michael T. H.; Nagase, Shigeru; Akasaka, Takeshi; Blom, Burgert; Ferrari, Erika; Tangoulis, Vassilis; Mayer, Cédric R; Klein, Axel; Stoumpos, Constantinos C.
- Abstract
This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years. After differences in chemical reactivity between EMFs and the corresponding empty fullerenes are discussed, cage-opening reactions of EMFs are examined. Then, the selective bisfunctionalization of EMFs is explained. Finally, single-bonding derivatization of EMFs is addressed. The diversity and applicability of the chemical functionalization of endohedral metallofullerenes are presented to readers worldwide.
- Subjects
METALLOFULLERENES; FULLERENES; HORIZON; PERICYCLIC reactions; ADDITION reactions; DERIVATIZATION
- Publication
Molecules, 2020, Vol 25, Issue 16, p3626
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules25163626