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- Title
Organic Salts and Merrifield Resin Supported [PM12O40]3− (M = Mo or W) as Catalysts for Adipic Acid Synthesis.
- Authors
Pisk, Jana; Agustin, Dominique; Poli, Rinaldo
- Abstract
Adipic acid (AA) was obtained by catalyzed oxidation of cyclohexene, epoxycyclohexane, or cyclohexanediol under organic solvent-free conditions using aqueous hydrogen peroxide (30%) as an oxidizing agent and molybdenum- or tungsten-based Keggin polyoxometalates (POMs) surrounded by organic cations or ionically supported on functionalized Merrifield resins. Operating under these environmentally friendly, greener conditions and with low catalyst loading (0.025% for the molecular salts and 0.001–0.007% for the supported POMs), AA could be produced in interesting yields.
- Subjects
ADIPIC acid; CYCLOHEXENE; CYCLOHEXANEDIONES; MOLYBDENUM; TUNGSTEN
- Publication
Molecules, 2019, Vol 24, Issue 4, p783
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules24040783