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- Title
Synthesis of Cyclic Carbonates from Epoxides and CO<sub>2</sub> under Mild Conditions Using a Simple, Highly Efficient Niobium-Based Catalyst.
- Authors
Monassier, Antoine; D'Elia, Valerio; Cokoja, Mirza; Dong, Hailin; Pelletier, Jérémie D. A.; Basset, Jean ‐ Marie; Kühn, Fritz E.
- Abstract
Like a sore thumb: Niobium stands out among neighboring transition metals for its catalytic performance in the synthesis of cyclic carbonates. Readily available NbCl5 is a very efficiENt catalyst for the preparation of industrially relevant carbonates at ambiENt temperature, low CO2 pressure, and low concENtrations. DMAP=N,N ‐ dimethylaminopyridine.
- Subjects
CARBON dioxide; CHEMICALS; CARBON offsetting; CHEMICAL synthesis; CARBONATES; NIOBIUM chlorides; CATALYSTS
- Publication
ChemCatChem, 2013, Vol 5, Issue 6, p1321
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.201200916