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- Title
Synthesis and Structural Diversity of Four Coordination Polymers with the Ligand 1-(3-Aminopropyl)-imidazole.
- Authors
Qi, Zhao‐Peng; Li, Pei‐Yu; Chen, Long; Li, Chang‐Jiang; Liu, Wei‐Bing; Cheng, Xing; Kang, Zong‐Hui
- Abstract
Four new metal complexes {[Cu(api)2(H2O)] ·(ClO4)2 ·CH3CN} n ( 1), [Cu(api)2(ClO4)2] n ( 2), [Cd(api)2(SCN)2] n ( 3) and [Ni(api)2(SCN)2] n ( 4) (api = 1-(3-Aminopropyl)-imidazole) were synthesized by reactions of api and different metal salts under different conditions. Interestingly, complexes 1- 3 exhibit various one dimensional (1D) double chain structures, while complex 4 shows a 2D layer structure. The results indicate that metal ions, anions, solvents, and the synthesis methods, have great influence on the formation and structure of the complexes.
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2013, Vol 639, Issue 2, p424
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201200414