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- Title
Composite mechanism of the catalytic hydrogenation of unsaturated hydrocarbons on hydrided magnesium intermetallides.
- Authors
Molchanov, V.; Goidin, V.; Buyanov, R.
- Abstract
Two temperature ranges are distinguished in the catalytic hydrogenation of unsaturated hydrocarbons on magnesium intermetallide hydrides. In the lower temperature range, the reaction proceeds by a composite mechanism, as is indicated by the fact that the rate of the catalytic hydrogenation of ethylene, n-butenes, and butadiene is equal to the rate of the reduction of these hydrocarbons with hydride hydrogen. It is assumed that, at higher temperatures, the reaction proceeds by a heterogeneous-homogeneous mechanism.
- Subjects
CATALYSIS; HYDROGENATION; HYDROCARBONS; MAGNESIUM; HYDRIDES; BUTADIENE
- Publication
Kinetics & Catalysis, 2006, Vol 47, Issue 5, p744
- ISSN
0023-1584
- Publication type
Article
- DOI
10.1134/S0023158406050132