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- Title
Stereocomplexed Poly(Limonene Carbonate): A Unique Example of the Cocrystallization of Amorphous Enantiomeric Polymers.
- Authors
Auriemma, Finizia; De Rosa, Claudio; Di Caprio, Maria Rosaria; Di Girolamo, Rocco; Ellis, W. Chadwick; Coates, Geoffrey W.
- Abstract
We report the cocrystallization of the regio- and stereoregular chiral copolymer poly(limonene carbonate). To the best of our knowledge, this marks the first example of an amorphous, enantiomerically pure polymer that becomes crystalline upon stereocomplexation with its complementary enantiomer. By analyzing X-ray powder diffraction data, we propose a packing model in which sheets of enantiopure chains interdigitate with layers of the opposite enantiomer, forming a 'steric zipper'.
- Subjects
LIMONENE; CARBONATES; CRYSTALLINE polymers; ENANTIOMERIC purity; COPOLYMERS
- Publication
Angewandte Chemie International Edition, 2015, Vol 54, Issue 4, p1215
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201410211