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- Title
Synthesis of Functional Isosorbide‐Based Polyesters and Polyamides by Passerini Three‐Component Polymerization.
- Authors
Sun, Xiaofei; Wang, Chengliang; Zhang, Xu; Zhang, Yan; Wang, Qingfu; Sun, Jingjiang
- Abstract
Environmental issues are becoming more and more prominent, and bio‐based polymers are essential to alleviate environmental degradation by replacing traditional polymers. With this context, a new family of functional isosorbide‐based polyesters and polyamides with high glass transition temperature are prepared via Passerini‐Three component polymerization (P‐3CP). To optimize the P‐3CP conditions, the influence of the polymerization solvent, temperature, feed ratio on the molar mass of final polymers are investigated. The higher molar mass (up to 10100 g/mol) and yield (>70 %) are achieved under very mild conditions (30 °C, standard atmosphere). Functional side groups, such as alkenyl, alkynyl and methyl ester, were introduced into polymer structure via P‐3CP by using functional isocyanides. The obtained polyesters and polyamides are characterized by nuclear magnetic resonance (NMR) and infrared (IR) spectroscopies, differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). All polymers are thermal stable and amorphous with variable glass transition temperatures (Tg). The obtained polyester has Tg up to 87.5 °C, while the Tg of polyamides (ISPA‐2) is detected to be 97.5 °C depending on the amide bonds in the polymer backbone and the benzene ring side groups. The cytotoxicity is investigated by the CCK‐8 assay against mBMSC cells to confirm the biological safety. Overall, this novel strategy provides an efficient approach to produce functional isosorbide‐based polyesters and polyamides, which are promising prospect for being applied to biodegradable materials.
- Subjects
POLYESTERS; POLYMERS; POLYAMIDES; THERMOGRAVIMETRY; GLASS transition temperature; BIODEGRADABLE materials; NUCLEAR magnetic resonance
- Publication
Chemistry - A European Journal, 2023, Vol 29, Issue 70, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202303005