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- Title
Transition‐Metal‐Free Synthesis of Polyfluoro‐Polyarylmethanes via Direct Cross‐Coupling of Polyfluoroarenes and Benzyl Chlorides.
- Authors
Zhou, Yu; Hu, Dandan; Zhang, Yuting; Cen, Qiyou; Dong, Zhi‐Bing; Zhang, Jun‐Qi; Ren, Hongjun
- Abstract
The transition‐metal‐free direct cross‐coupling between polyfluoroarenes and benzyl chlorides is reported. In this strategy, a variety of polyfluoro di‐, tri‐ and tetra‐arylmethanes was efficiently prepared with good to excellent yields in the presence of Mg turnings via a one‐pot procedure. Significantly, this method provides a general approach for the synthesis of polyfluorinated polyarylmethanes.
- Subjects
BENZYL chloride; GRIGNARD reagents
- Publication
Chemistry - A European Journal, 2023, Vol 29, Issue 19, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202203427