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- Title
Pd/Gorlos‐Phos‐Catalyzed Chemoselective Amination of Bromophenyl Chlorides with Primary Arylamines.
- Authors
Duan, Xinyu; Song, Yulong; Fu, Chunling; Ma, Shengming
- Abstract
With the readily available Gorlos‐Phos as a ligand, halogenated diarylamines were prepared efficiently from Pd‐catalyzed monoamination of bromophenyl chlorides and primary arylamines, tolerating functional groups such as aldehyde, ketone, nitrile, fluorine, sulphonyl and trifluoromethyl groups. The formation of the amination of the C−Cl bond and diamination products were not observed.
- Subjects
AMINATION; AROMATIC amines; ARYL chlorides; CHLORIDES; FUNCTIONAL groups; KETONES; ALDEHYDES
- Publication
Helvetica Chimica Acta, 2022, Vol 105, Issue 1, p1
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.202100173