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- Title
4‐Chloro‐2‐azaadamantane N‐Oxyl (4‐Cl‐AZADO): A Readily Preparable Organocatalyst for NO<sub>x</sub> Co‐catalyzed Aerobic Alcohol Oxidation.
- Authors
Nagasawa, Shota; Sasano, Yusuke; Iwabuchi, Yoshiharu
- Abstract
Concise synthesis and structure‐activity relationships study of 4‐substituted 2‐azaadamantane N‐oxyls reveals that 4‐chloro‐2‐azaadamantane N‐oxyl (4‐Cl‐AZADO) is an efficient organocatalyst toward the aerobic oxidation of alcohols in the presence of NOx as a co‐catalyst. The organocatalyst was easily synthesized from 2‐adamantanone in five steps, and it showed high activity compared with many previously reported nitroxyl radical catalysts.
- Subjects
ALCOHOL oxidation; STRUCTURE-activity relationships; ALCOHOL; NITROXYL; CATALYSTS
- Publication
Asian Journal of Organic Chemistry, 2023, Vol 12, Issue 4, p1
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.202300031