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- Title
Synthetic Applications of Ambiphilic C‐acylimines in Organic Synthesis.
- Authors
Pareek, Abhishek; Singh, Garima; Yaragorla, Srinivasarao
- Abstract
C‐acylimines are generally obtained through condensation/dehydration of simple and readily available glyoxals and amines. The structure resembles naturally occurring biological substances due to the presence of the imino group (−N=C−). Chemically, C‐acylimines exhibit ambiphilic reactivity, and hence, their synthetic chemistry becomes more attractive and viable for the synthesis of various aza‐cyclic/heterocyclic compounds, including their asymmetric counterpart. Therefore, many synthetic methodologies were developed from these readily preparable C‐acylimines. Surprisingly, there is no account/review available on this specific topic. Hence we present here an account of all the synthetic endeavours developed from C‐acylimines to synthesize small molecules and complex systems using various strategies.
- Subjects
IMINO group; SMALL molecules; ASYMMETRIC synthesis; ORGANIC synthesis; CONDENSATION
- Publication
Asian Journal of Organic Chemistry, 2022, Vol 11, Issue 9, p1
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.202200395