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- Title
BH, CH, and BC Bond Activation: The Role of Two Adjacent Agostic Interactions.
- Authors
Cassen, Audrey; Gloaguen, Yann; Vendier, Laure; Duhayon, Carine; Poblador ‐ Bahamonde, Amalia; Raynaud, Christophe; Clot, Eric; Alcaraz, Gilles; Sabo ‐ Etienne, Sylviane
- Abstract
Tuning the nature of the linker in a L∼BHR phosphinoborane compound led to the isolation of a ruthenium complex stabilized by two adjacent, δ-CH and ε-Bsp2H, agostic interactions. Such a unique coordination mode stabilizes a 14-electron 'RuH2P2' fragment through connected σ-bonds of different polarity, and affords selective BH, CH, and BC bond activation as illustrated by reactivity studies with H2 and boranes.
- Subjects
CARBON-hydrogen bonds; AGOSTIC interaction; BORANES; RUTHENIUM compounds; POLARITY
- Publication
Angewandte Chemie, 2014, Vol 126, Issue 29, p7699
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201404753