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- Title
Rh/Pd Catalysis with Chiral and Achiral Ligands: Domino Synthesis of Aza-Dihydrodibenzoxepines.
- Authors
Friedman, Adam A.; Panteleev, Jane; Tsoung, Jennifer; Huynh, Vaizanne; Lautens, Mark
- Abstract
The article discusses the domino synthesis of aza-dihydrodibenzoxepines using the rhodium/palladium-(Rh/Pd) catalysis with chiral and achiral ligands. It notes the combination of Pd-catalyzed carbon-oxygen (C-O) coupling and Rh-catalyzed arylation to develop a domino process for the compound. Moreover, it mentions the discovery of domino reactivity in the synthesis.
- Subjects
AZA compound synthesis; LIGANDS (Chemistry); RHODIUM catalysts; PALLADIUM catalysts; REACTIVITY (Chemistry); ARYLATION
- Publication
Angewandte Chemie, 2013, Vol 125, Issue 37, p9937
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201303659