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- Title
Double Dynamic Structural Change Enabling Tricolor Chromism by the Realization of Apparent Two‐Electron Transfer to Skip the Open‐Shell State.
- Authors
Harimoto, Takashi; Sugai, Yuka; Sugawara, Kazuma; Suzuki, Takanori; Ishigaki, Yusuke
- Abstract
Most redox systems generally cannot avoid the involvement of open‐shell species upon generating multiply charged species, which often reduces reversibility in multi‐color electrochromic systems. In this study, we newly synthesized octakis(aminophenyl)‐substituted pentacenebisquinodimethane (BQD) derivatives and their hybrids with alkoxyphenyl analogues. Thanks to apparent two‐electron transfer accompanied by double dramatic changes in the structure of the arylated quinodimethane skeleton, the dicationic and tetracationic states were generated and isolated quantitatively because of the negligible steady‐state concentration of intermediary open‐shell species such as monocation or trication radicals. When two electrophores with different donating abilities are attached to the BQD skeleton, a dicationic state with a different color can be isolated in addition to the neutral and tetracationic states. For these tetracations, an interchromophore interaction induces a red‐shift of the NIR absorptions, thus realizing tricolor UV/Vis/NIR electrochromic behavior involving only closed‐shell states.
- Subjects
OXIDATION-reduction reaction; DRAMATIC structure; ELECTROCHROMIC substances; QUINODIMETHANE; SKELETON; REDSHIFT
- Publication
Chemistry - A European Journal, 2023, Vol 29, Issue 51, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202301476