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- Title
Field-Supported Single-Molecule Magnets of Type [Co(bzimpy)X<sub>2</sub>].
- Authors
Rajnák, Cyril; Varga, Filip; Titiš, Ján; Moncoľ, Ján; Boča, Roman
- Abstract
Magnetic properties of pentacoordinate complexes of the type [Co(bzimpy)X2], X = Cl and Br, were investigated in DC and AC modes. The DC data shows sizeable zero-field splitting for these complexes. The AC susceptibility data confirms slow magnetic relaxation at the applied DC field with two relaxation channels. The low-frequency relaxation time is as slow as τLF ≈ 0.1-0.3 s for the Cl and Br complexes at T = 1.9 K.
- Subjects
METAL complexes; MAGNETIC properties of metals; SINGLE molecule magnets; CARBON monoxide; MAGNETIC susceptibility; MAGNETIC relaxation
- Publication
European Journal of Inorganic Chemistry, 2017, Vol 2017, Issue 13, p1915
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201601279