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- Title
Palladium chloride catalyzed photochemical Heck reaction.
- Authors
Waghmode, Suresh B.; Arbuj, Sudhir S.; Wani, Bina N.; Gopinath, C.S.
- Abstract
PdCl2 catalyzed carbon-carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV-visible light. The results demonstrated that UV-visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.
- Subjects
PALLADIUM compounds; CHLORIDES; HECK reaction; CATALYSIS; CARBON-carbon bonds; ARYL halides; PHOTOCHEMISTRY
- Publication
Canadian Journal of Chemistry, 2013, Vol 91, Issue 5, p348
- ISSN
0008-4042
- Publication type
Article
- DOI
10.1139/cjc-2012-0377