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- Title
Enantioselective Ammonolysis of Phenylglycine Methyl Ester with Lipase-Pluronic Nanoconjugate in Tertiary Butanol.
- Authors
Wu, Xiaoling; Wang, Rui; Zhang, Yifei; Ge, Jun; Liu, Zheng
- Abstract
Asymmetrical ammonolysis of ( R)- and ( S)-phenylglycine methyl ester was carried out by using a lipase (CALB)-polymer (Pluronic) nanoconjugate as the catalyst, displaying a 11-fold increased catalytic rate compared to the free CALB in tertiary butanol. Graphical Abstract: The asymmetrical ammonolysis of ( R)- and ( S)-phenylglycine methyl ester was accomplished using a lipase-Pluronic nanoconjugate, displaying a 11-fold higher catalytic rate compared to the free lipase.[Figure not available: see fulltext.]
- Subjects
ENANTIOSELECTIVE catalysis; AMMONOLYSIS; PHENYLGLYCINE; METHYL formate; LIPASES; COMPARATIVE studies; CATALYSIS
- Publication
Catalysis Letters, 2014, Vol 144, Issue 8, p1407
- ISSN
1011-372X
- Publication type
Article
- DOI
10.1007/s10562-014-1289-2