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- Title
Palladium(0)-Catalyzed Cross-Couplings of 2-Bromophosphinine.
- Authors
Kostenko, Nataliya; Ericsson, Cecilia; Engqvist, Magnus; Gonzalez, Susana Villa; Bayer, Annette
- Abstract
A new Negishi-type cross-coupling of 2-bromophosphinine has been developed. The new method expands the scope of palladium-catalyzed couplings to monobromophosphinines, which have been considered as poor substrates so far. Moreover, aryl-, alkenyl-, and alkynylzinc bromides were found to be effective coupling partners.
- Subjects
COUPLING agents (Chemistry); PALLADIUM; SUBSTRATES (Materials science); BROMIDES; PHOSPHORINE; PRINCIPAL components analysis
- Publication
European Journal of Organic Chemistry, 2013, Vol 2013, Issue 22, p4756
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201300710