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- Title
Phenol degradation using the mixed material clay/Fe immobilized on glass slides.
- Authors
Taketa, Lidiane; Ignachewski, Franciély; Villalba, Juan; Anaissi, Fauze; Fujiwara, Sérgio
- Abstract
The mixed material clay/Fe was prepared and immobilized on glass slides and calcined at 550 and 750 °C. The calcined material X-ray powder pattern (XRD) diffractograms indicate that there is no intercalation of iron compounds inside the lamella clay. The experimental design revealed that the most suitable phenol degradation conditions were obtained using the material calcined at 750 °C in a pH 7 and 140 mg/L of hydrogen peroxide solution. The material MMAFe750 showed excellent performance as a catalyst for Fenton-like reaction; in 125 min, 50 % of phenol was removed in the absence of leaching-supported iron. These results indicate that the reaction occurs by a heterogeneous process. Furthermore, the material showed no loss of catalytic activity after five degradation studies. It was noted that the adsorption of phenol in the synthesized materials does not occur and the mixed material is strongly adsorbed onto glass slides.
- Subjects
X-ray diffraction; IRON compounds; HYDROGEN peroxide; BIODEGRADATION of phenols; ADSORPTION (Chemistry)
- Publication
Environmental Science & Pollution Research, 2015, Vol 22, Issue 2, p894
- ISSN
0944-1344
- Publication type
Article
- DOI
10.1007/s11356-014-3239-3