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- Title
A 6,11,16-Triarylbiphenylcorrole with an adj-CCNN Core: Stabilization of an Organocopper(III) Complex.
- Authors
Adinarayana, B.; Thomas, Ajesh P.; Suresh, Cherumuttathu H.; Srinivasan, A.
- Abstract
An adj-dicarbacorrole with CCNN in the core is achieved by replacing the bipyrrole moiety by a simple polycyclic aromatic hydrocarbon, such as biphenyl unit. Spectroscopic studies and structural analyzes confirm the absence of macrocyclic aromatization, thus leading to overall nonaromatic character. The trianionic core is effectively utilized to stabilize a copper(III) ion to form an organocopper complex.
- Subjects
ORGANOCOPPER compounds; PYRROLES; MOLECULAR structure of polycyclic aromatic hydrocarbons; BIPHENYL compounds; STRUCTURAL analysis (Science); MACROCYCLIC compounds; AROMATIZATION
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 36, p10624
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201503347